Iron disilicide
Names | |
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IUPAC name Iron disilicide | |
Other names Iron(VIII) silicide | |
Identifiers | |
CAS Number |
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3D model (JSmol) |
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ChemSpider |
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ECHA InfoCard | 100.031.507 ![]() |
EC Number |
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PubChem CID |
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CompTox Dashboard (EPA) |
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InChI
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Properties | |
Chemical formula | FeSi2 |
Molar mass | 112.016 g/mol |
Appearance | gray tetragonal crystals[1] |
Density | 4.74 g/cm3[1] |
Melting point | 1,220 °C (2,230 °F; 1,490 K)[1] |
Band gap | 0.87 eV (ind.)[2] |
Electron mobility | 1200 cm2/(V·s) |
Structure | |
Crystal structure | Orthorhombic[3] |
Space group | Cmca (No. 64), oS48 |
Lattice constant | a = 0.9863 nm, b = 0.7791 nm, c = 0.7833 nm |
Formula units (Z) | 16 |
Hazards | |
GHS labelling: | |
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Warning | |
H315, H319, H335 | |
Flash point | Non-flammable |
Related compounds | |
Other cations | Cobalt disilicide Manganese disilicide Titanium disilicide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). ![]() ![]() ![]() Infobox references |
Chemical compound
Iron disilicide (FeSi2) is an intermetallic compound, a silicide of iron that occurs in nature as the rare mineral linzhiite. At room temperature it forms orthorhombic crystals (β phase), which convert into a tetragonal α phase upon heating to 970 °C.[3]
See also
References
- ^ a b c Haynes, William M., ed. (2016). CRC Handbook of Chemistry and Physics (97th ed.). CRC Press. p. 4.67. ISBN 9781498754293.
- ^ Rizzi, A.; Rösen, B. N. E.; Freundt, D.; Dieker, Ch.; Lüth, H.; Gerthsen, D. (1995). "Heteroepitaxy of β-FeSi2 on Si by gas-source MBE". Physical Review B. 51 (24): 17780–17794. Bibcode:1995PhRvB..5117780R. doi:10.1103/PhysRevB.51.17780. PMID 9978811.
- ^ a b Dusausoy, Y.; Protas, J.; Wandji, R.; Roques, B. (1971). "Structure cristalline du disiliciure de fer, FeSi2-β". Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry. 27 (6): 1209–1218. doi:10.1107/S0567740871003765.
- v
- t
- e
- H2Fe(CO)4
- Na2Fe(CO)4
- Fe(CO)5
- Fe2(CO)9
- Fe3(CO)12
- Fe(CO)3CH3COC2H2C6H6
- FeH
Organoiron(I) compounds |
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- Fe3C
- FeH2
- Mg2FeH6
- FeF2
- FeCl2
- Fe(ClO4)2
- FeBr2
- FeI2
- FeO
- Fe(OH)2
- FeS
- FeSO4
- (NH4)2Fe(SO4)2·6H2O
- FeSe
- FeSeO4
- Fe(NO3)2
- Fe3(PO4)2
- FeSi2
- Fe(BF4)2
- FeCr2O4
- FeMoO4
- FeTiO3
- FeCO3
- FeC2O4
- Fe(C2H3O2)2
- Fe(C3H5O3)2
- FeC6H6O7
- FeC12H22O14
- FeI2(CO)4
Organoiron(II) compounds |
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- Fe3O4
- Fe3S4
Organoiron(III) compounds |
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- FeF4
- K2FeO4
- BaFeO4